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Organic Arsenicals

Learn about organic arsenicals in drinking water, their potential health risks, and benefits, and tips on managing safe water supply to reduce exposure.

Reviewed by Content Team

Head of Content, Daniel Goren

Updated June, 5

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Organic Arsenicals

 
Understanding Organic Arsenicals in Drinking Water
 

Organic arsenicals are chemical compounds containing arsenic bonded primarily to carbon atoms. Arsenic itself naturally occurs in various forms in the earth's crust and can infiltrate water resources. However, arsenic becomes a serious environmental and health concern when it enters drinking water supplies, including the organic forms known as organic arsenicals.

Arsenicals may occur naturally due to geological activities or may enter the water supply due to agricultural runoff, industrial discharge, or improper waste management. Agricultural practices commonly use organic arsenicals compounds as herbicides and pesticides for crop and livestock production. Given their tendency to infiltrate groundwater and aquifers, communities, including major urban areas such as St Louis and Nashville, may occasionally encounter these substances, albeit typically at relatively low levels.

 
Health Risks Associated with Organic Arsenicals in Drinking Water
 

Exposure to organic arsenicals in drinking water can lead to a variety of health concerns. The severity of these health issues largely depends on the amount of arsenic present in water, duration of exposure, and individual health factors. Potential health impacts include:

  • Increased Cancer Risk: Regular and prolonged exposure to arsenicals, even in small amounts, is associated with an increased risk of cancers, such as cancers of the skin, bladder, liver, kidneys, lung, and prostate.
  • Neurological Problems: Long-term arsenic exposure has been linked to problems such as cognitive decline, memory impairment, numbness, tingling sensations, and other nerve-related symptoms.
  • Skin Disorders: Prolonged arsenic exposure can lead to various skin problems including hyperpigmentation, thickening of the skin, keratosis, dermatitis, and other dermatological disorders.
  • Reproductive and Developmental Issues: Organic arsenicals contamination can also pose risks to pregnant women or young children, potentially causing developmental delays and birth defects.
  • Cardiovascular Disease: Long-term ingestion of arsenic can elevate the chances of developing heart disease, hypertension, and related cardiovascular illnesses.

Thus, regular monitoring and preventive measures to control contamination levels are crucial for maintaining public health.

 
Potential Benefits and Uses of Organic Arsenicals
 

Despite their health risks, organic arsenicals have historically been utilized in various beneficial agricultural and industrial applications, primarily due to their effectiveness as pesticides, herbicides, and animal dietary supplements. Certain organic arsenical compounds have been effectively used to:

  • Agricultural Enhancements: Organic arsenicals are widely used to control weeds and pests that threaten crop productivity and quality. Controlled application can help maximize crop yields and thus ensure food security.
  • Livestock Production: Organic arsenicals have historically been used as feed additives, influencing livestock growth rates and preventing disease-spreading organisms.
  • Economic Efficiency: Cost-effective pest management helps improve economic outcomes for agricultural producers, thus benefiting community economics indirectly by lowering overall production costs.

However, the potential environmental and health risks of arsenicals have led regulatory agencies worldwide to significantly restrict or completely ban various organic arsenic compounds in agriculture, animal feed, and other sectors.

 
Protecting Yourself from Organic Arsenicals in Drinking Water
 

Preventing arsenic exposure at a community and household level involves practical steps that can significantly reduce risks:

  • Water Testing: Routine laboratory testing of drinking water from private wells or municipal supplies to accurately detect and measure potential arsenic levels.
  • Regularly Maintaining Water Systems: Ensuring that household water treatment systems and filtration mechanisms are routinely serviced by contamination and filtration professionals, such as experienced plumbing specialists available in regions like St Louis and Nashville.
  • Water Treatment Options: Choosing effective water treatment technologies such as reverse osmosis, activated alumina, or advanced filtration systems specifically designed to remove arsenicals and other contaminants from drinking water.
  • Awareness and Education: Educate family members and community groups on arsenic-related health risks as well as the importance of safe drinking water practices to avoid prolonged exposure.

Ensuring regular water testing, proper filtration systems, and preventive maintenance will significantly reduce exposure risks and help foster healthier communities.

 
Conclusion
 

Organic arsenicals, while providing some economic and agricultural benefits, carry significant potential health risks primarily through chronic exposure in drinking water. Awareness, proper monitoring, and investing in robust water treatment systems can protect your household and community, ensuring safe, healthy, and sustainable water use.

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Common Signs of Excess Organic Arsenicals in Water

 
Garlic-Like Odor and Taste in Water
 
Excessive presence of organic arsenicals often imparts a distinctive garlic-like odor and taste to water. This particular sign occurs because some organic arsenic compounds release volatile arsenic byproducts that carry this distinct smell when dissolved and activated by water. Persistent garlic-like odors or tastes should not be ignored, as they typically indicate higher concentrations of arsenic-based compounds.
 
Skin Irritation and Dermatological Symptoms
 
Skin irritation, including redness, itching, and various forms of dermatitis, can be clear indicators of elevated organic arsenicals in water. People exposed regularly to contaminated water sources can develop visible symptoms over time due to the adverse interaction of arsenical compounds with skin tissues, resulting in dryness, rashes, discoloration, and chronic sores.
 
Digestive System Discomfort and Gastrointestinal Issues
 
Chronic exposure to high levels of organic arsenicals in water commonly causes gastrointestinal symptoms, such as:

  • Nausea and persistent stomach discomfort
  • Vomiting episodes or frequent bouts of nausea after drinking the water
  • Diarrhea or digestive disruptions occurring regularly

These symptoms occur because organic arsenicals irritate the lining of the stomach and intestines, causing digestive distress.
 
Neurological and Behavioral Changes
 
Elevated exposure to organic arsenicals has been associated with neurological signs such as:

  • Headaches, dizziness, or chronic fatigue
  • Tingling in extremities or numbness sensations
  • Memory disturbances and confusion
  • Mood alterations, anxiety, or unusual irritability

These signs may appear after prolonged exposure to water containing high organic arsenicals, due to their neurotoxic properties affecting the nervous system.
 
Respiratory Issues and Unique Symptoms
 
Long-term exposure to water contaminated with organic arsenicals can lead to unusual respiratory problems. Common signs include:

  • Persistent cough or frequent respiratory irritation
  • Breathing difficulties or feeling shortness of breath intermittently after water exposure
  • Increased susceptibility to respiratory infections due to weakened immunity

Respiratory symptoms occur because arsenicals, inhaled or ingested over time, can damage lung tissues and irritate respiratory passages.
 
Chronic Health Conditions and Long-Term Risks
 
Exposure to excess organic arsenicals in water over prolonged periods can significantly increase the risk of chronic health conditions such as:

  • Damage to the liver or kidneys, resulting in impaired organ function
  • Development of certain cancers, particularly skin, bladder, lung, kidney, and liver cancers due to carcinogenic effects
  • Hematological abnormalities, such as reduced blood cell count, leading to anemia and general weakness
  • Increased rates of cardiovascular diseases, including hypertension, heart disease, and peripheral vascular conditions

These chronic health issues reflect long-term exposure to arsenicals and indicate severe contamination that necessitates urgent water testing and treatment.
 
Testing Recommendations if Signs are Present
 
To confirm the presence of an excess of organic arsenicals in water, the following steps are recommended:

  • Professional laboratory testing for arsenic concentration to verify precise levels and toxicity
  • Periodic assessment of water sources, particularly if any symptom mentioned is identified
  • Consultation with health and environmental professionals to interpret test results and recommend the appropriate actions

If any of the above signs appear, immediate water quality testing and, if necessary, mitigation strategies should be initiated promptly to safeguard health.

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How Organic Arsenicals Changes the Taste and Smell of Your Water

 

How Organic Arsenicals in Water Affect Your Appliances

 

Organic arsenicals, derived from arsenic-containing pesticides, fertilizers, industrial runoff, and naturally occurring soil deposits, frequently find their way into groundwater and domestic water systems. Although less well-known than metals like calcium or iron, these substances can subtly damage household appliances, leading to efficiency loss, increased operation costs, and shorter appliance lifespans. Understanding how organic arsenicals impact appliances and taking measures to prevent or correct it can save you money and frustration. Here’s how arsenicals affect appliances and what you can do about it:

 

Appliance Damage From Corrosion

 

Organic arsenicals can slowly lead to corrosion or deterioration in metal-based appliances. Over prolonged periods, constant exposure of these compounds (even in trace amounts) to metallic surfaces can accelerate oxidation and corrosion of internal metal parts, such as heating coils, water tanks, valves, pipes, and fittings. This corrosion weakens structural integrity, causing leakages and eventual breakdown. Additionally, the corrosion can also lead to discoloration and staining of metallic surfaces that affect appliance aesthetics.

  • Water Heaters: Arsenicals induce corrosion on heating elements, storage tank interiors, reducing efficiency and necessitating frequent replacements.
  • Washing Machines and Dishwashers: Corrosive damage to hoses, pumps, and metallic drum interiors results in leaks, poor cleaning performance, and mechanical failures.
  • Coffee Makers and Kettles: Corrosion on internal metal components leads to water leakage and shortened appliance useful life.
  • Plumbing Fixtures and Pipes: Long-term arsenical exposure deteriorates internal pipes and valves, causing reduced flow, leaks, or contamination due to rust buildup.

 

Deposits and Clogging Issues

 

Organic arsenicals, especially when combining with other minerals and metals in water (such as calcium or iron), can form small solid sediments. These sediments accumulate in internal appliance passages, reducing the ability of water to flow freely through valves, nozzles, and tubes. Over time, buildup leads to reduced appliance efficiency, increased maintenance, damage to pumps and motors, and ultimately, appliance failure.

  • Dishwashers: Small particles block spray nozzles and clog drainage systems.
  • Water Heaters: Accumulation of arsenicals deposits within tanks reduces efficiency and increases energy costs.
  • Ice Machines & Refrigerators: Deposits form in water lines and valves, reducing ice production and resulting in unusual tastes or odors.

 

Reduced Energy Efficiency and Increased Costs

 

When organic arsenicals cause corrosion and buildup, affected appliances become more inefficient. Corrosion reduces the heat-exchange capacity and water flow, causing the appliance to consume more energy to deliver the same performance. Over extended periods, this inefficiency raises monthly electricity and water bills, resulting in significantly increased overall household expenditure.

  • Increased electricity use due to appliances working harder to compensate for reduced efficiency.
  • Costs associated with frequent appliance replacements, repair work, and professional maintenance.

 

Potential Health Concerns and Additional Risks

 

Though generally lower risk than inorganic arsenic, continuous exposure to water containing organic arsenicals can raise concerns regarding ingestion from residual contamination within appliances, fixtures, or water supply systems. Appliance corrosion can also indirectly contribute to elevated arsenic concentrations in drinking water because corroded metallic surfaces may release more metal contaminants back into household water.

  • Possible exposure from internal corrosion and contamination of drinking water appliances.
  • Health risks associated with prolonged consumption of arsenical-contaminated water.

 

What to Do About Organic Arsenicals in Your Water

 

1. Get Your Water Tested Regularly

Regular water testing by certified laboratories helps monitor the presence and concentration of organic arsenicals. Identifying contaminants early allows homeowners to implement proactive solutions rather than dealing with costly appliance repairs later on.

 

2. Invest in Effective Water Treatment Systems

Installing a good water filtration system or treatment method, such as activated carbon filters, reverse osmosis systems, or ion-exchange resins, can effectively remove most organic arsenicals and other damaging pollutants from domestic water supplies, dramatically extending the lifespan and improving the efficiency of home appliances.

  • Reverse Osmosis Systems: Highly efficient at removing dissolved contaminants, including arsenicals, from drinking and cooking water.
  • Activated Carbon Filters: Reduce or eliminate organic contaminants effectively.
  • Ion-exchange Resins: Help capture and remove arsenicals and other trace metals effectively from household water supplies.

 

3. Regular Maintenance and Cleaning of Appliances

Regular appliance maintenance, inspections, and physically removing accumulated deposits minimize the harmful effects and buildup caused by organic arsenicals. Flush water heaters regularly, descale coffee machines or kettles, and frequently inspect plumbing fixtures to remove corrosion and maintain optimal performance and efficiency.

 

4. Consider Replacing Metal Components with Corrosion-Resistant Options

Gradually replacing susceptible appliance components (such as plumbing pipes, fittings, heating elements) with materials less prone to corrosion (stainless steel, PEX tubing, or specialized composite materials) reduces the overall risk of arsenic-related corrosion. This often results in significantly longer-lasting, more efficient appliances and greatly reduced maintenance costs.

  • Stainless steel pipes, fittings, and appliances provide excellent protection against both arsenicals and other types of waterborne corrosion.
  • Plastic pipes (PEX) are durable, corrosion-resistant, and provide a reliable alternative to traditional copper or metallic plumbing.

 

Conclusion

 

Organic arsenicals in household water can significantly affect the efficiency, lifespan, safety, and operating costs of your appliances. However, by regularly testing your water, employing filtration systems, performing preventive maintenance, and using corrosion-resistant appliance materials, you can effectively minimize these harmful effects and maintain healthier, more efficient home appliances. The time, effort, and expense invested in these proactive solutions consistently outweigh the cost and inconvenience of appliance failure, inefficiency, and unforeseen health concerns associated with arsenical contamination.

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How Organic Arsenicals Changes the Taste and Smell of Your Water

 
Understanding What Are Organic Arsenicals
 
Organic arsenicals are compounds containing arsenic atoms bonded with carbon atoms, which occur either naturally through biological processes or result from the agricultural and industrial use of arsenic-containing substances. Organic arsenicals often find their way into water sources due to agricultural runoff, industrial discharges, pesticide residues, animal feeding additives, and natural decomposition processes. When these compounds enter the water supply, they play a significant role in changing both the taste and smell of water.
 
Why and How Organic Arsenicals Affect Taste and Smell
 
Organic arsenicals directly interact with the natural chemistry of water supplies, altering sensory perception of the water. Although elemental arsenic itself is odorless and tasteless at normal concentrations, organic arsenic compounds often form interactions that produce distinct changes in water's sensory characteristics. Here's why and how taste and smell changes occur:

  • Interference with Natural Minerals: Organic arsenicals can chemically bond or react with naturally occurring dissolved minerals (such as iron, manganese, sulfur, and calcium carbonates) in water. Such chemical interactions can create new compounds or change the form of existing minerals, thus altering the flavor profile, often resulting in an unusual metallic or bitter aftertaste.
  • Bacterial Action and Formation of By-Products: Bacteria present naturally in water sources or water treatment systems can metabolize organic arsenicals, leading to the generation of secondary compounds. These bacterial degradation products of arsenicals may carry strong odors and flavors, typically described as musty, sulfurous, or even fishy.
  • Chemical Transformations in Treatment Systems: During water treatment processes, chlorine or other disinfectants may interact chemically with organic arsenicals, resulting in alteration or breakdown into smaller or different organic and inorganic species, each capable of imparting distinctive odors or tastes to water.
  • Formation of Volatile Organic Compounds (VOCs): Under certain conditions, some microbial activity or chemical reactions influenced by organic arsenicals can form volatile organic compounds. VOCs often have pungent smells reminiscent of solvents, chemicals, or rotten eggs, substantially affecting consumer perception and overall sensory quality of drinking water.
  Description of Typical Taste and Smell Changes Caused by Organic Arsenicals   Typically, the presence of organic arsenicals manifests in various recognizable ways that consumers frequently find unpleasant:
  • Metallic or Bitter Taste: One of the most common taste alterations noticed is a metallic or bitter flavor. Even small quantities of arsenic-based products dissolved into water can significantly intensify this unwanted metallic taste sensation, making water less palatable.
  • Musty and Earthy Odors: If organic arsenicals undergo microbial breakdown processes, the result can often be an earthy or musty smell. This smell, while usually harmless at low to moderate levels, can significantly impact consumer perception negatively and cause doubts regarding water safety and purity.
  • Sulfurous or Fishy Odor and Taste: Some organic arsenic-based compounds, when chemically altered or biologically processed, could produce volatile sulfur-containing compounds. These chemical reactions lead to water possessing odors and tastes reminiscent of rotten eggs, sulfur, or even a fish-like aroma.
  Factors Influencing the Severity of Smell and Taste Changes   Not all cases of water contamination with organic arsenicals produce the same intensity of odor or taste. Several factors determine the severity and characteristics of these sensory changes:
  • Concentration of Organic Arsenicals in Water: Higher levels of arsenic compounds typically result in significantly more pronounced taste and smell effects.
  • Chemical Composition of the Water: The water's chemical characteristics, like pH, mineral content, presence of chlorine, or disinfectants, greatly influence the reactions and thus the taste and smell changes observed.
  • Water Temperature: Higher temperatures generally accelerate chemical reactions and microbial activities, leading quickly to noticeable changes in smell and taste.
  • Duration of Exposure and Contact Time: Longer exposure times give arsenical compounds more opportunities for reactions, chemical transformations, and microbial decomposition, all intensifying the alteration of sensory properties.
  Impact of Organic Arsenicals on Health and Water Quality   The changes in smell and taste caused by organic arsenicals do more than negatively impact water enjoyment; they signal possible contamination that holds risk to human health. Prolonged ingestion of arsenic and certain arsenical compounds—even at moderate concentrations—can pose serious long-term health threats. These health concerns include:
  • Increased risk of cancers (notably skin, bladder, kidney, liver, and lung cancers)
  • Damage to the cardiovascular and neurological systems
  • Digestive disturbances and possible liver and kidney impairment
  • Development of chronic skin conditions such as hyperkeratosis and pigmentation changes
Additionally, aesthetic alterations in smell and taste are often early indicators of water contamination, prompting consumers to seek further testing and appropriate remedies.   Recommendations to Address Taste and Smell Issues due to Organic Arsenicals   If you suspect that organic arsenical compounds have impacted your water quality, consider taking several vital steps:
  • Contact a reputable certified laboratory to thoroughly test and determine the levels of organic arsenicals present in the water.
  • Implement treatment systems designed explicitly for arsenicals, such as specialized filtration methods, activated carbon treatments, reverse osmosis, or advanced oxidation processes.
  • Regularly maintain and monitor water treatment and purification systems, ensuring removal of contamination and prevention of its build-up.
  • Consider changes or improvements in local land-use management practices or agricultural activity if the source of contamination is evident from runoff.
  Conclusion: Remaining Vigilant About Organic Arsenicals in Your Water   Organic arsenicals significantly influence the sensory characteristics of water—altering taste and smell due to various chemical interactions and transformations. Recognizing early signs (such as metallic or sulfurous tastes and odors) is crucial because they could indicate deeper contamination issues potentially harmful to health. Taking swift action includes professional testing, careful management, and advanced water treatment methods. By remaining aware and proactive, you ensure the water you drink remains safe, healthy, and pleasant-tasting.

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